A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

TSOUREAS, Nikolaos, HADDOW, Mairi F., HAMILTON, Alexander and OWEN, Gareth R. (2009). A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide. Chemical Communications (18), 2538-2540.

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Official URL: http://dx.doi.org/10.1039/B822678D
Link to published version:: 10.1039/B822678D

Abstract

The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)3}−] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

Item Type: Article
Research Institute, Centre or Group: Biomolecular Sciences Research Centre
Identification Number: 10.1039/B822678D
Depositing User: Jamie Young
Date Deposited: 29 May 2015 10:47
Last Modified: 29 May 2015 10:47
URI: http://shura.shu.ac.uk/id/eprint/9918

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