TSOUREAS, Nikolaos, HADDOW, Mairi F., HAMILTON, Alexander and OWEN, Gareth R. (2009). A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide. Chemical Communications (18), 2538-2540.
Abstract
The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)3}−] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.
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