A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

Tsoureas, Nikolaos; Haddow, Mairi F.; Hamilton, Alexander; Owen, Gareth R.

A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

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TSOUREAS, Nikolaos, HADDOW, Mairi F., HAMILTON, Alexander and OWEN, Gareth R. (2009). A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide. Chemical Communications (18), 2538-2540. [Article]

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Abstract

The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)3}−] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

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Official URL:

http://dx.doi.org/10.1039/B822678D

Research Institute, Centre or Group - Does NOT include content added after October 2018:

Biomedical Research Centre

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2538-2540

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Identification Number:

10.1039/B822678D

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