Rational design of p-type thermoelectric PbTe: Temperature dependent sodium solubility

AMINORROAYA YAMINI, Sima, IKEDA, T., LALONDE, A., PEI, Y., DOU, S.X. and SNYDER, G.J. (2013). Rational design of p-type thermoelectric PbTe: Temperature dependent sodium solubility. Journal of Materials Chemistry A, 1 (31), 8725-8730. [Article]

Abstract
We develop a solid understanding of the temperature-dependent solubility of sodium in p-type PbTe, the most efficient thermoelectric material. The maximum solubility of sodium telluride (NaTe) in PbTe is measured to be 1.4 ± 0.3 at% and the heat of solution is evaluated as 26+19-11 kJ mol-1 that addresses fundamental issues regarding the formation of nano-precipitates. © 2013 The Royal Society of Chemistry.
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