A new family of sulfur-rich ligands based on the dmit system: synthesis and metal complexation of 4–4'-covalently bridged bis(2-thioxo-1,3-dithiol-5-thiolato) units

ALLEN, D. W., BERRIDGE, R., BRICKLEBANK, N., CERRADA, E., LIGHT, M. E., HURSTHOUSE, M. B., LAGUNA, M., MORENO, A. and SKABARA, P. J. (2002). A new family of sulfur-rich ligands based on the dmit system: synthesis and metal complexation of 4–4'-covalently bridged bis(2-thioxo-1,3-dithiol-5-thiolato) units. Journal of the Chemical Society, Dalton Transactions.

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Abstract

The synthesis of a new series of sulfur-rich ligands is reported. These compounds, which are related to the dmit2-(2-thioxo-1,3-dithiol-4,5-dithiolato) structure, comprise two 2-thioxo-1,3-dithiol-5-thiolato units linked by a bridging unit at the 4-position of the heterocycle via a dithioether spacer unit. Complexation reactions have been carried out on a variety of metal centres; dialkyl tin and gold(I) derivatives have been isolated and fully characterised. The X-ray crystal structure of an octahedral Ni(II) complex, involving two coordinating pyridine molecules, is presented.

Item Type:	Article
Research Institute, Centre or Group - Does NOT include content added after October 2018:	Biomedical Research Centre
Identification Number:	https://doi.org/10.1039/b201615j
Depositing User:	Ann Betterton
Date Deposited:	21 Feb 2008
Last Modified:	18 Mar 2021 21:45
URI:	https://shura.shu.ac.uk/id/eprint/407

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