A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale

BOYD, TM, ANDREA, KA, BASTON, K, JOHNSON, Alice, RYAN, DE and WELLER, AS (2019). A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale. Chemical Communications, 56 (3), 482-485. [Article]

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30020:604175
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Abstract
A simple Co(ii)-based amine-borane dehydropolymerisation catalyst system is reported that operates at low loadings, to selectively give (H2BNMeH)n polymer on scale, with catalyst control over Mn, narrow dispersities and low residual metal content.
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