A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale

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BOYD, TM, ANDREA, KA, BASTON, K, JOHNSON, Alice, RYAN, DE and WELLER, AS (2019). A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale. Chemical Communications, 56 (3), 482-485. [Article]

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30020:604175

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30020:604175

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Abstract

A simple Co(ii)-based amine-borane dehydropolymerisation catalyst system is reported that operates at low loadings, to selectively give (H2BNMeH)n polymer on scale, with catalyst control over Mn, narrow dispersities and low residual metal content.

More Information

Official URL:

https://pubs.rsc.org/en/content/articlelanding/202...

Uncontrolled Keywords:

03 Chemical Sciences; Organic Chemistry

Page Range:

482-485

Event Location:

England

Identifiers

Identification Number:

10.1039/c9cc08864d