An octahedral tetrachlorido Fe(ii) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures

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RUSBRIDGE, E.K., PENG, Y., POWELL, A.K., ROBINSON, D. and FITZPATRICK, Anthony (2018). An octahedral tetrachlorido Fe(ii) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures. Dalton Transactions, 47 (23), 7644-7648. [Article]

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27714:588757

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Abstract

© 2018 The Royal Society of Chemistry. An air stable, neutral Fe(ii) complex with four equatorial chlorido ligands has been stabilised through a serendipitous redox process and in situ ligand protonation. A three-dimensional non-covalent network composed of halogen bonding and π-π stacking promotes magnetic exchange interactions though the lattice. The electronic structure has been investigated using DFT.

More Information

Official URL:

https://pubs.rsc.org/en/content/articlelanding/201...

Uncontrolled Keywords:

0302 Inorganic Chemistry; 0307 Theoretical and Computational Chemistry; 0399 Other Chemical Sciences; Inorganic & Nuclear Chemistry

Page Range:

7644-7648

Event Location:

England

Identifiers

Identification Number:

10.1039/c8dt01401a