Synthesis and characterization of a novel semiconducting N-alkylpyridinium benzimidazolate betaine-TCNQ charge-transfer complex

ALLEN, D. W., HAWKRIGG, J., TRACEY, S. M., RAY, A. K. and HASSAN, A. K. (1997). Synthesis and characterization of a novel semiconducting N-alkylpyridinium benzimidazolate betaine-TCNQ charge-transfer complex. Synthetic Metals, 87 (1), 89-91. [Article]

Abstract
The reaction of the 2-(1-methylpyridinium-3-yl) benzimidazolate betaine with an equimolar proportion of tetracyanoquinodimethane (TCNQ) in the presence of acetonitrile results in the formation of a novel semiconducting black microcrystalline adduct having a room-temperature conductivity of 4.7 x 10(-3) S cm(-1).
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