KHAN, Akram (1991). The Claisen rearrangement of 2-phenylsulfinyl-2-propenyl phenyl ethers –A new route to functionalized phenols and 2-methylbenzofurans. Bulletin of the chemical society of Japan, 64 (12), 3682-3686.
Full text not available from this repository.Abstract
The hitherto unknown Claisen rearrangement of 2-phenylsulfinyl-2-propenyl phenyl ethers to the corresponding 2-(2-phenylsulfinyl-2-propenyl)phenols is reported. The latter compounds underwent Michael reactions with a variety of nucleophiles to provide functionalized phenolic adducts. O-Alkylation of the initial rearrangement products with 3-bromo-2-phenylsulfinyl-1-propene and 2,3-dibromo-l-propene followed by [3,3] sigmatropic rearrangement provided a promising route to 7-substituted 2-methylbenzofurans.
Item Type: | Article |
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Departments - Does NOT include content added after October 2018: | Health and Well-being > Department of Bioscience |
Identification Number: | https://doi.org/10.1246/bcsj.64.3682 |
Page Range: | 3682-3686 |
Depositing User: | Louise Beirne |
Date Deposited: | 20 Sep 2018 12:31 |
Last Modified: | 18 Mar 2021 10:45 |
URI: | https://shura.shu.ac.uk/id/eprint/22610 |
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