A new hybrid scorpionate ligand : a study of the metal–boron bond within metallaboratrane complexes

OWEN, Gareth R., HUGH GOULD, P., CHARMANT, Jonathan P. H., HAMILTON, Alexander and SAITHONG, Saowanit (2010). A new hybrid scorpionate ligand : a study of the metal–boron bond within metallaboratrane complexes. Dalton Transactions, 39 (2), 392-400.

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Official URL: http://dx.doi.org/10.1039/B911651F
Link to published version:: 10.1039/B911651F

Abstract

A new boron-based hybrid scorpionate ligand based upon one 2-mercaptopyridine (mp) and two 1-methyl-imidazoyl-2-thione (mt) units, Na[HB(mt)(2)(mp)] has been prepared. This new ligand together with the recently reported ligand K[HB(mp)(3)] have been used to prepare analogues of the original metallaboratrane complex [Ru(CO)(PPh(3)){kappa(4)-SSBS-B(mt)(3)}]. The effect of tautomerisation of the ligand arms upon the electronic properties of the boron and metal centres is examined in an attempt to probe further the nature of the metal-boron bond within metallaboratrane complexes.

Item Type: Article
Research Institute, Centre or Group: Biomolecular Sciences Research Centre
Identification Number: 10.1039/B911651F
Depositing User: Jamie Young
Date Deposited: 29 May 2015 10:25
Last Modified: 29 May 2015 10:25
URI: http://shura.shu.ac.uk/id/eprint/9923

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