ZENG, X. B., UNGAR, G., SPELLS, S. J., BROOKE, G. M., FARREN, C. and HARDEN, A. (2002). Crystal-amorphous polymer interface studies by neutron and X-ray scattering on labeled binary ultralong alkanes. Physical review letters, 90 (15), 155508-1.Full text not available from this repository.
The recently discovered stable semicrystalline phase in binary ultralong alkanes is studied by small-angle neutron and x-ray scattering. Either the shorter or the longer alkane has (CD2)11CD3 ends. It is confirmed that chains are tilted in the crystal layer and found that ca. seven end carbons of the shorter alkane are amorphous. It is also established that the longer chains protrude from the crystal at both ends and that their end groups are preferentially located in the middle of the amorphous layer, suggesting gradual dissipation of orientational order of the chains exiting the crystal.
|Additional Information:||©2003 The American Physical Society|
|Research Institute, Centre or Group:||Materials and Engineering Research Institute > Polymers Nanocomposites and Modelling Research Centre > Polymers, Composites and Spectroscopy Group|
|Depositing User:||Ann Betterton|
|Date Deposited:||16 Aug 2007|
|Last Modified:||09 Aug 2010 14:13|
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