Structure-property relationships in BaTiO3-BiFeO3-BiYbO3 Ceramics

FETEIRA, Antonio, LUISMAN, Luke, SCHILEO, Giorgio, DELUCA, Marco and REICHMANN, Kaus (2013). Structure-property relationships in BaTiO3-BiFeO3-BiYbO3 Ceramics. In: Ceramic Interconnect and Ceramic Microsystems Technologies (CICMT 2013)., Orlando, USA, 23-26th April 2013. (Unpublished)

Full text not available from this repository.

Abstract

Ba1-xBixTi1-xYbx/2Fex/2O3 ceramics were fabricated by the solid state reaction method. X-ray diffraction analysis show 0 ≤ x ≤ 0.04 ceramics to have an average crystal structure described by the non-centrosymmetric tetragonal P4mm space group, whereas x ≥ 0.08 ceramics are consistent with a centrosymmetric cubic perovskite (space group Pm-3m). Coexistence of both tetragonal and cubic symmetries is observed for x=0.06. Raman spectroscopy analysis corroborate a change in average structure with increasing x, but also show the local crystal symmetry for x ≥ 0.08 ceramics to deviate from the idealized cubic perovskite structure. Dielectric data show a ferroelectric-to-relaxor crossover, which occurs in conjunction with the change in both the average and local crystal symmetry as indicated by X-ray and Raman data. For x ≥ 0.08, BBTYbFe ceramics exhibit weak-relaxor behavior, which is also accompanied by a shift of the permittivity maxima towards higher temperatures with increasing x.

Item Type: Conference or Workshop Item (Paper)
Research Institute, Centre or Group: Materials and Engineering Research Institute > Structural Materials and Integrity Research Centre > Centre for Corrosion Technology
Depositing User: Antonio Feteira
Date Deposited: 15 Nov 2013 13:58
Last Modified: 15 Nov 2013 13:58
URI: http://shura.shu.ac.uk/id/eprint/7463

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year

View more statistics