Ferroelectric aging and recoverable electrostrain in BaTi0.98Ca0.02O2.98 ceramics

ZHANG, Lwi, BEN, Liubin, THAKUR, Om Prakash, FETEIRA, Antonio, MOULD, Andrew G., SINCLAIR, Derek C. and WEST, Anthony R. (2008). Ferroelectric aging and recoverable electrostrain in BaTi0.98Ca0.02O2.98 ceramics. Journal of the American Ceramic Society, 91 (9), 3101-3104.

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Official URL: http://dx.doi.org/10.1111/j.1551-2916.2008.02570.x
Link to published version:: https://doi.org/10.1111/j.1551-2916.2008.02570.x
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    BaTi0.98Ca0.02O2.98 (BTC) ceramics where Ca2+ acts as an acceptor dopant show ferroelectric aging, reversible domain switching, and a nonlinear recoverable electrostrain of ∼0.04% at ∼11 kV/cm. This behavior is attributed to the mobility of oxide-ion vacancies created by the acceptor doping mechanism and a tendency for the defect symmetry to align with the crystal symmetry. The recoverable strain in unpoled ceramics is of comparable magnitude to that obtained from the linear piezoelectric effect in poled hard-PZT ceramics at a similar applied field. These preliminary results demonstrate the potential of BTC as a ‘Pb-free’ ceramic to achieve significant recoverable electrostrain.

    Item Type: Article
    Research Institute, Centre or Group - Does NOT include content added after October 2018: Materials and Engineering Research Institute > Structural Materials and Integrity Research Centre > Centre for Corrosion Technology
    Identification Number: https://doi.org/10.1111/j.1551-2916.2008.02570.x
    Page Range: 3101-3104
    Depositing User: Hilary Ridgway
    Date Deposited: 06 Jun 2012 14:40
    Last Modified: 18 Mar 2021 09:45
    URI: https://shura.shu.ac.uk/id/eprint/5327

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