Structural and magnetic properties of a novel ferrocenyl-diiodine

ALLEN, D. W., BERRIDGE, R., BRICKLEBANK, N., FORDER, S. D., PALACIO, F., COLES, S. J., HURSTHOUSE, M. B. and SKABARA, P. J. (2003). Structural and magnetic properties of a novel ferrocenyl-diiodine. Inorganic chemistry, 42 (13), p. 3975.

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The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented "double" charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

Item Type: Article
Research Institute, Centre or Group: Biomolecular Sciences Research Centre
Identification Number:
Depositing User: Ann Betterton
Date Deposited: 21 Feb 2008
Last Modified: 13 Jun 2017 12:44

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