Catalytic transformation of the gases evolved during the thermal decomposition of HDPE using acid-activated and pillared clays

BREEN, C. and LAST, P. M. (1999). Catalytic transformation of the gases evolved during the thermal decomposition of HDPE using acid-activated and pillared clays. Journal of Materials Chemistry, 9 (3), 813-818.

Full text not available from this repository.
Link to published version:: https://doi.org/10.1039/a808882i
Related URLs:

    Abstract

    HDPE was thermally decomposed in a thermobalance and the evolved gases were passed through a bed of catalyst. Two acid activated clays of different structure were used, ie. sepiolite (SEP), which is a fibrous clay mineral, and smectite (K10) which is a layered mineral. In addition two pillared smectites were studied one which was pillared with an Al species (AZA) and the other with an Al/Fe-species (FAZA). The thermal and catalytic decomposition of HDPE was studied under dynamic (35 to 650 degrees C at 10 degrees C min(-1)) and isothermal (60 min at 420 degrees C) conditions. The evolved gases were analysed using TC-OTM-GC-MS. The thermal decomposition of HDPE yielded characteristic quartets of peaks assigned to n-alkanes, alk-l-enes, alk-x-enes and alpha,omega-dienes in the range C-4-C-20 Species of higher molecular weight than C-20 were not detected. All four catalysts converted the alkenes present in the thermally generated off gases into light gases and aromatic species including respectable quantities of toluene, xylenes, tri- and tetra-methylbenzenes. Ethylbenzenes and naphthalenes were produced to a lesser extent. AZA and FAZA produced the largest yield of aromatics and sepiolite is considered to produce significant quantities of low molecular weight gases in the isothermal process. The product distribution over sepiolite suggested that there were fewer dehydrocyclisation sites on this catalyst. None of the catalysts used was capable of cracking the saturated alkanes.

    Item Type: Article
    Research Institute, Centre or Group - Does NOT include content added after October 2018: Materials and Engineering Research Institute > Polymers Nanocomposites and Modelling Research Centre > Polymers, Composites and Spectroscopy Group
    Identification Number: https://doi.org/10.1039/a808882i
    Page Range: 813-818
    Depositing User: Jill Hazard
    Date Deposited: 14 May 2010 11:05
    Last Modified: 13 Jun 2017 12:46
    URI: http://shura.shu.ac.uk/id/eprint/1842

    Actions (login required)

    View Item View Item

    Downloads

    Downloads per month over past year

    View more statistics