Complexes of heterocyclic thiones and group 12 metals: Part VI. Preparation and characterisation of complexes of cadmium(II) halides with 1-methylimidazoline-2(3H)-thione, 1,3-thiazolidine-2-thione and 1,3-benzothiazoline-2-thione. Crystal structures of polymeric (1,3-thiazolidine-2-thione)cadmium(II) chloride, bis(1,3-thiazolidine-2-thione)cadmium(II) iodide and monomeric bis(1-methylimidazoline-2(3H)-thione)cadmium(II) bromide

BELL, N. A., CLEGG, W., COLES, S. J., CONSTABLE, C. P., HARRINGTON, R. W., HURSTHOUSE, M. B., LIGHT, M. E., RAPER, E. S., SAMMON, C. and WALKER, M. R. (2004). Complexes of heterocyclic thiones and group 12 metals: Part VI. Preparation and characterisation of complexes of cadmium(II) halides with 1-methylimidazoline-2(3H)-thione, 1,3-thiazolidine-2-thione and 1,3-benzothiazoline-2-thione. Crystal structures of polymeric (1,3-thiazolidine-2-thione)cadmium(II) chloride, bis(1,3-thiazolidine-2-thione)cadmium(II) iodide and monomeric bis(1-methylimidazoline-2(3H)-thione)cadmium(II) bromide. Inorganica Chimica Acta, 357 (7), 2091-2099.

Full text not available from this repository.
Link to published version:: https://doi.org/10.1016/j.ica.2003.10.036

Abstract

Reactions of 1-methylimidazoline-2(3H)-thione (meimz2SH), 1,3-thiazolidine-2-thione (tzdSH) and 1,3-benzothiazoline- 2-thione (bztzSH) with cadmium(II) halides in ethanol solutions result in the formation of 1:1 complexes for the chloride, both 1:1 and 2:1 complexes for the bromide, and only 2:1 complexes for the iodide. Spectroscopic evidence confirms the exocyclic sulfur atom to be the donor in all cases. Cadmium(II) acetate and the heterocyclic ligands in the presence of triethylamine form the insoluble deprotonated complexes. The structure of (tzdSH)CdCl2, consists of double halogen-bridged chains, linked into sheets via (NHCl)-Cl-... interactions and with the heterocycle coordinated to the metal via the exocyclic sulfur atom. Thus each cadmium is approximately octahedrally surrounded by one sulfur, 2 two-coordinate and 3 three-coordinate chlorine atoms. In contrast (tzdSH)(2)CdI2, forms chains via (IS)-S-... interactions; the metal is tetrahedrally coordinated by two sulfur and two iodine atoms. The structure of (meimz2SH)(2)CdBr2, consists of discrete complex molecules with essentially tetrahedrally coordinated Cd and no significant intermolecular interactions; the six molecules in the asymmetric unit are related by pseudo-symmetry and are very similar except for variation in the orientation of the heterocyclic substituents. (C) 2003 Elsevier B.V. All rights reserved.

Item Type: Article
Research Institute, Centre or Group - Does NOT include content added after October 2018: Materials and Engineering Research Institute > Advanced Coatings and Composites Research Centre > Polymers, Composites and Spectroscopy Group
Identification Number: https://doi.org/10.1016/j.ica.2003.10.036
Page Range: 2091-2099
Depositing User: Jill Hazard
Date Deposited: 12 Apr 2010 11:23
Last Modified: 18 Mar 2021 21:30
URI: https://shura.shu.ac.uk/id/eprint/1579

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year

View more statistics