A Powerful Aluminum Catalyst for the Synthesis of Highly Functional Organic Carbonates

WHITEOAK, Christopher, KIELLAND, Nicola, LASERNA, Victor, ESCUDERO-ADÁN, Eduardo C., MARTIN, Eddy and KLEIJ, Arjan W. (2013). A Powerful Aluminum Catalyst for the Synthesis of Highly Functional Organic Carbonates. Journal of the American Chemical Society, 135 (4), 1228-1231.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja311053h
Link to published version:: 10.1021/ja311053h

Abstract

An aluminum complex based on an amino triphenolate ligand scaffold shows unprecedented high activity (initial TOFs up to 36 000 h–1), broad substrate scope, and functional group tolerance in the formation of highly functional organic carbonates prepared from epoxides and CO2. The developed catalytic protocol is further characterized by low catalyst loadings and relative mild reaction conditions using a cheap, abundant, and nontoxic metal.

Item Type: Article
Identification Number: 10.1021/ja311053h
Depositing User: Christopher Whiteoak
Date Deposited: 01 Apr 2016 10:49
Last Modified: 01 Apr 2016 10:49
URI: http://shura.shu.ac.uk/id/eprint/11783

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