Easily accessible bifunctional Zn(salpyr) catalysts for the formation of organic carbonates

MARTÍN, C., WHITEOAK, Christopher, MARTIN, E., MARTÍNEZ BELMONTE, M., ESCUDERO-ADÁN, E. C. and KLEIJ, A. W. (2014). Easily accessible bifunctional Zn(salpyr) catalysts for the formation of organic carbonates. Catalysis Science & Technology, 4 (6), 1615-1621.

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Official URL: http://pubs.rsc.org/en/content/articlehtml/2014/cy...
Link to published version:: 10.1039/C3CY01043K

Abstract

Alkylated Zn(salpyr) complexes (salpyr = N,N′-bis[salicylidene]-3,4-pyridinediamine) were prepared and used as catalyst precursors for the formation of cyclic carbonates from a range of (functional) epoxides and CO2. Reaction conditions were optimized to achieve good isolated yields of the targeted products. The molecular structure of the most active bifunctional Zn(salpyr) derivative was also resolved by X-ray diffraction.

Item Type: Article
Identification Number: 10.1039/C3CY01043K
Depositing User: Christopher Whiteoak
Date Deposited: 05 Apr 2016 14:53
Last Modified: 25 Apr 2016 15:02
URI: http://shura.shu.ac.uk/id/eprint/11775

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