MANDAL, Paranjayee, EHIASARIAN, Arutiun and HOVSEPIAN, Papken (2015). Isothermal and dynamic oxidation behaviour of Mo−W doped carbon-based coating. Applied Surface Science, 353, 1291-1309.
Ehiasarian_Isothermal_and_dynamic_oxidation_behaviour_of_Mo.pdf - Accepted Version
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The oxidation behaviour of Mo−W doped carbon-based coating (Mo−W−C) is investigated in elevated temperature (400°C−1000°C). Strong metallurgical bond between Mo−W−C coating and substrate prevents any sort of delamination during heat-treatment. Isothermal oxidation tests show initial growth of metal oxides at 500°C, however graphitic nature of the as-deposited coating is preserved. The oxidation progresses with further rise in temperature and the substrate is eventually exposed at 700°C. The performance of Mo−W−C coating is compared with a state-of-the-art coating, which shows preliminary oxidation at 400°C and local delamination of the coating at 500°C leading to substrate exposure. The graphitisation starts at 400°C and the diamond-like structure is completely converted into the graphite-like structure at 500°C. Dynamic oxidation behaviour of both the coatings is investigated using Thermo-gravimetric analysis carried out with a slow heating rate of 1°C/min from ambient temperature to 1000°C. Mo−W−C coating resists oxidation up to ~800°C whereas delamination of coating is observed beyond ~380°C. In summary, Mo−W−C coating provides improved oxidation resistance at elevated temperature compared to coating.
|Additional Information:||Available online 15 July 2015|
|Research Institute, Centre or Group:||Materials and Engineering Research Institute > Thin Films Research Centre > Nanotechnology Centre for PVD Research|
|Depositing User:||Yashodhan Purandare|
|Date Deposited:||25 Jun 2015 09:26|
|Last Modified:||19 Oct 2016 23:50|
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