Shape-, size-, and functional group-selective binding of small organic guests in a paramagnetic coordination cage

TUREGA, Simon, WHITEHEAD, Martina, HALL, Benjamin R., MEIJER, Anthony J. H. M., HUNTER, Christopher A. and WARD, Michael D. (2013). Shape-, size-, and functional group-selective binding of small organic guests in a paramagnetic coordination cage. Inorganic Chemistry, 52 (2), 1122-1132.

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Abstract

A cubic coordination cage acts in MeCN as a host for neutral organic guests which contain an H-bond-accepting group that interacts with the internal surface of the cage. The different thermodynamic contributions to guest recognition and the kinetics of both guest binding and reorganization inside the cavity have been analyzed in detail by 1H NMR spectroscopy, which is facilitated by the paramagnetism of the host cage.

Item Type:	Article
Additional Information:	Publication Date (Web): January 9, 2013
Research Institute, Centre or Group - Does NOT include content added after October 2018:	Biomedical Research Centre
Identification Number:	https://doi.org/10.1021/ic302498t
Page Range:	1122-1132
Depositing User:	Jamie Young
Date Deposited:	30 Jun 2015 13:26
Last Modified:	18 Mar 2021 18:45
URI:	https://shura.shu.ac.uk/id/eprint/10010

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