Flexible scorpionates for transfer hydrogenation : the first example of their catalytic application.

TSOUREAS, Nikolaos, OWEN, Gareth R, HAMILTON, Alexander and ORPEN, A Guy (2008). Flexible scorpionates for transfer hydrogenation : the first example of their catalytic application. Dalton Transactions (43), 6039-6044.

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Abstract

Rhodium and iridium complexes of flexible scorpionate ligands based on azaindole were synthesised in good yields. The complexes were characterised in solution and in the solid state. Structural characterisation revealed a B-H-metal interaction, which is retained in solution. Given the greater flexibility of the ligand and potential cooperative effect of boron, the complexes were tested for their activity in the transfer hydrogenation of ketones.

Item Type:	Article
Research Institute, Centre or Group - Does NOT include content added after October 2018:	Biomedical Research Centre
Identification Number:	https://doi.org/10.1039/B809247H
Page Range:	6039-6044
Depositing User:	Jamie Young
Date Deposited:	29 May 2015 11:20
Last Modified:	18 Mar 2021 23:15
URI:	https://shura.shu.ac.uk/id/eprint/9930

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