A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

TSOUREAS, Nikolaos, HADDOW, Mairi F., HAMILTON, Alexander and OWEN, Gareth R. (2009). A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide. Chemical Communications (18), 2538-2540.

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Abstract

The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)3}−] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

Item Type:	Article
Research Institute, Centre or Group - Does NOT include content added after October 2018:	Biomedical Research Centre
Identification Number:	https://doi.org/10.1039/B822678D
Page Range:	2538-2540
Depositing User:	Jamie Young
Date Deposited:	29 May 2015 10:47
Last Modified:	18 Mar 2021 10:00
URI:	https://shura.shu.ac.uk/id/eprint/9918

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