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RUSBRIDGE, E.K., PENG, Y., POWELL, A.K., ROBINSON, D. and FITZPATRICK, Anthony (2018). An octahedral tetrachlorido Fe(ii) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures. Dalton Transactions, 47 (23), 7644-7648.
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Fitzpatrick_OctahedralTetrachloridoComplex(AM).pdf - Accepted Version All rights reserved. Download (1MB) | Preview |
Abstract
© 2018 The Royal Society of Chemistry. An air stable, neutral Fe(ii) complex with four equatorial chlorido ligands has been stabilised through a serendipitous redox process and in situ ligand protonation. A three-dimensional non-covalent network composed of halogen bonding and π-π stacking promotes magnetic exchange interactions though the lattice. The electronic structure has been investigated using DFT.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 0302 Inorganic Chemistry; 0307 Theoretical and Computational Chemistry; 0399 Other Chemical Sciences; Inorganic & Nuclear Chemistry |
| Identification Number: | https://doi.org/10.1039/c8dt01401a |
| Page Range: | 7644-7648 |
| SWORD Depositor: | Symplectic Elements |
| Depositing User: | Symplectic Elements |
| Date Deposited: | 18 May 2021 14:49 |
| Last Modified: | 18 May 2021 14:49 |
| URI: | https://shura.shu.ac.uk/id/eprint/27714 |
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