Conversion of oxiranes and CO2 to organic cyclic carbonates using a recyclable, bifunctional polystyrene-supported organocatalyst

WHITEOAK, Christopher, HENSELER, Andrea H., AYATS, Carles, KLEIJ, Arjan W. and PERICÀS, Miquel A. (2013). Conversion of oxiranes and CO2 to organic cyclic carbonates using a recyclable, bifunctional polystyrene-supported organocatalyst. Green chemistry, 16 (3), 1552-1559.

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Abstract

The development of a heterogeneous one-component bifunctional catalyst system able to catalyse the conversion of carbon dioxide and oxiranes to organic cyclic carbonates at low temperature (45 °C) is reported. The bifunctional system can be easily recycled and reactivated when required. When compared with other heterogeneous organocatalysts for the same transformation, the reported catalyst is active at much milder temperatures, thus emphasising the optimal sustainability profile of the new catalyst system.

Item Type:	Article
Identification Number:	https://doi.org/10.1039/C3GC41919C
Page Range:	1552-1559
Depositing User:	Christopher Whiteoak
Date Deposited:	05 Apr 2016 15:01
Last Modified:	18 Mar 2021 22:45
URI:	https://shura.shu.ac.uk/id/eprint/11776

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