An octahedral tetrachlorido Fe(ii) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures

RUSBRIDGE, E.K., PENG, Y., POWELL, A.K., ROBINSON, D. and FITZPATRICK, Anthony (2018). An octahedral tetrachlorido Fe(ii) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures. Dalton Transactions, 47 (23), 7644-7648.

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Official URL: https://pubs.rsc.org/en/content/articlelanding/201...
Link to published version:: https://doi.org/10.1039/c8dt01401a
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    Abstract

    © 2018 The Royal Society of Chemistry. An air stable, neutral Fe(ii) complex with four equatorial chlorido ligands has been stabilised through a serendipitous redox process and in situ ligand protonation. A three-dimensional non-covalent network composed of halogen bonding and π-π stacking promotes magnetic exchange interactions though the lattice. The electronic structure has been investigated using DFT.

    Item Type: Article
    Uncontrolled Keywords: 0302 Inorganic Chemistry; 0307 Theoretical and Computational Chemistry; 0399 Other Chemical Sciences; Inorganic & Nuclear Chemistry
    Identification Number: https://doi.org/10.1039/c8dt01401a
    Page Range: 7644-7648
    SWORD Depositor: Symplectic Elements
    Depositing User: Symplectic Elements
    Date Deposited: 18 May 2021 14:49
    Last Modified: 18 May 2021 14:49
    URI: http://shura.shu.ac.uk/id/eprint/27714

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